In 2004, Grammy Award-winning, DJ/Producer Benny Benassi chose Alice Edun among hundreds of vocalists for his "Benny Wants You" appeal program. As a result, she recorded lead vocals in 2005 on "Who's Knockin?" by FB. The record contains mixes by Ferry Corsten and Benny Benassi and was released through Dance Therapy, Holland.

In 2007, Alice Edun made her solo debut with "Put 'Em Up," released in the U.S. by Robbins Entertainment. It reached the 2 spot on Billboard's Hot Dance Airplay Chart. "Put 'Em Up" also went on to become the most-aired track on American, Dance radio the same year and was supported by Judge Jules on BBC Radio 1 in the UK.